Advancing the Reforming Process with Raman Technology in Refineries
Hydrocrackers are integral to modern refining, transforming heavy hydrocarbons into lighter, high-value products like diesel, jet fuel, and naphtha. This conversion process not only increases the value of crude oil fractions but also helps meet the growing demand for cleaner, high-quality fuels. Precise monitoring of hydrocracker operations is essential to optimize efficiency, manage sulfur content, and ensure consistent product quality.
Your Simple, Cost-efficient Turnkey Solution
At HORIBA Process Instruments, we understand the unique demands of your industry. Our cutting-edge solutions are designed to deliver accurate, real-time insights for process optimization, safety, and compliance. From oil and gas to pharmaceuticals and beyond, we provide reliable tools that empower you to monitor critical parameters, reduce operational costs, and improve product quality.
Naphtha Fractionation for Reforming
Before reforming, the naphtha splitter fractionation tower separates naphtha into light and heavy fractions. Light naphtha primarily consists of C5 and C6 hydrocarbons, including straight-chain paraffins and cyclic aliphatic compounds, while heavy naphtha contains C7 to C9 hydrocarbons. This separation ensures that heavy naphtha—rich in naphthenes—provides an optimal feedstock for catalytic reforming, where these heavier molecules are more effectively converted into high-octane aromatics.

Isomerization: Boosting Octane with Branched-Chain Hydrocarbons
The isomerization unit complements the reforming process by converting straight-chain hydrocarbons into branched-chain isomers, enhancing the fuel's octane rating. Feedstocks like normal butanes, pentanes, and hexanes undergo chemical rearrangement under controlled temperature and pressure conditions with the aid of a catalyst.
This process transforms normal paraffins into branched-chain compounds, such as isobutane, isopentane, and isohexane, which are valuable components in high-octane gasoline. Any unreacted paraffins are recycled to maximize yield. Depending on the refinery's needs, the isomerate product can either serve as a high-octane blending component or as a feedstock for the alkylation process, where it is used to create even higher-value compounds like isobutane.
Process Raman Benefits:
- Predict and monitor key feedstock properties, including n-butane, n-pentane, and n-hexane, ensuring consistent quality and optimal feed composition for maximum isomerization efficiency
- Precisely predict critical product properties like i-butane, i-pentane, and i-hexane to ensure high-octane fuel production and maximize product value in blending or further processing
- Continuously monitor the isomerization process with real-time predictions of octane and Reid Vapor Pressure (RVP), ensuring compliance with fuel specifications while reducing rework and operational risks
- Ensure precise control of light ends fractionation to optimize downstream processes, including alkylation and blending, improving overall refinery efficiency and profitability
- Achieve real-time process control with measurements delivered in less than two minutes, enabling faster decision-making and improved operational responsiveness
Resources
At HORIBA Process Instruments, we are committed to more than just delivering cutting-edge Raman technology—we aim to empower you with the knowledge and tools to excel in your industry. Our Resources & Knowledge Base is your go-to hub for expert insights, technical documentation, and best practices to optimize your process monitoring and analysis.
Learn MoreRefinery Applications
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